Smoke Detectors and Americium
(Updated July 2014)
- Most smoke detectors which operate alarms contain an artificially produced radioisotope: americium-241.
- Americium-241 is made in nuclear reactors, and is a decay product of plutonium-241.
Smoke detectors/alarms are important safety devices, because of their obvious potential to save lives and property. There are two types of smoke detector commonly available in many countries.
One type uses the radiation from a small amount of radioactive material to detect the presence of smoke or heat sources. These 'ionisation chamber' smoke detectors are the most popular, because they are inexpensive and are sensitive to a wider range of fire conditions than the other type. They contain some americium.
The other type of detector does not contain radioactive material; it uses a photoelectric sensor to detect the change in light level caused by smoke. This type is more expensive to purchase and install, and is less effective in some circumstances.
The element americium (atomic number 95) was discovered in 1945 during the Manhattan Project in USA. The first sample of americium was produced by bombarding plutonium with neutrons in a nuclear reactor at the University of Chicagoa.
Americium-241, with a half-life of 432 years, was the first americium isotope to be isolated, and is the one used today in most domestic smoke detectors. Am-241 decays by emitting alpha particles and gamma radiation to become neptunium-237.
Americium dioxide, AmO2, was first offered for sale by the US Atomic Energy Commission in 1962 and the price of US$1500 per gram has remained virtually unchanged since. One gram of americium oxide provides enough active material for more than three million household smoke detectorsb.
The most common application of americium is of the Am-241 isotope as an ionisation source in smoke detectors, and most of the several kilograms of americium recovered each year is used in this way at present.
However, with constraint on the supply of Pu-238 alternative, the European Space Agency is now planning to use Am-241 in radioisotope thermoelectric generators (RTGs) for space missions, and the National Nuclear Laboratory in UK is gearing up to supply it in multi-kilogram quantities from aged civil plutonium, where it is a decay product of Pu-241.
In combination with beryllium, Am-241 is also used as a neutron source in non-destructive testing of machinery and equipment, and as a thickness gauge in the glass industry. Beryllium produces neutrons as it captures the alpha particles from AmO2. AmBe neutron sources have many applications including measuring soil moisture.
Operation of smoke detectors
The vital ingredient of household smoke detectors is a very small quantityc of Am-241 as americium dioxide (AmO2).
Americium-241 emits alpha particles and low energy gamma raysd. The alpha particles emitted by the Am-241 collide with the oxygen and nitrogen in air in the detector's ionisation chamber to produce charged particles (ions). A low-level electric voltage applied across the chamber is used to collect these ions, causing a steady small electric current to flow between two electrodes. When smoke enters the space between the electrodes, the smoke particles attach to the charged ions, neutralizing them. This causes the number of ions present – and therefore the electric current – to fall, which sets off an alarm.
The radiation dose to the occupants of a house from a domestic smoke detector is essentially zero, and in any case very much less than that from natural background radiation. The alpha particles are absorbed within the detector, while most of the gamma rays escape harmlessly. The small amount of radioactive material that is used in these detectors is not a health hazard and individual units can be disposed of in normal household wastee.
Even swallowing the radioactive material from a smoke detector would not lead to significant internal absorption of Am-241. Americium dioxide is insoluble, so will pass through the digestive tract without delivering a significant radiation dose. (Americium-241 is however a potentially dangerous isotope if it is taken into the body in soluble form. It decays by both alpha activity and gamma emissions and it would concentrate in the skeleton).
Formation of americium
Typical used fuel from a power reactor contains about 1% plutonium. Of this, about 10-14% is the plutonium-241 isotope, which has a half-life of only 14 years, decaying to Am-241 through emission of beta particles. Hence old civil plutonium has significant amounts of it. Am-241 has a half-life of 432 years, emitting alpha particles and gamma radiation to become neptunium-237.
The plutonium-241 is formed in any nuclear reactor by neutron capture from uranium-238. The detailed steps are:
- U-238 + neutron => U-239
- U-239 by beta decay => Np-239
- Np-239 by beta decay =>Pu-239
- Pu-239 + neutron => Pu-240
- Pu-240 + neutron => Pu-241
Pu-241 will decay both in the reactor and subsequently to form Am-241. Note that military plutonium, which is produced to have little Pu-240, will have even less Pu-241 and cannot be used as a source of americium.
It is of interest (and some significance in recycling spent fuel) that if too much Am-241 builds up in plutonium separated from spent fuel, it cannot readily be used in the manufacture of mixed oxide (MOX) fuel because it is too radioactive for handling in a normal MOX fuel fabrication plant. For instance, the Sellafield MOX Plant in the UK could handle plutonium containing up to 3% Am-241, hence up to six years old (any more would need special shielding).
a. Americium is a silvery metal, which tarnishes slowly in air and is soluble in acid. Its most stable isotope, Am-243, has a half-life of over 7500 years. [Back]
b. The activity of Am-241 is 127 GBq/g (3.43 Ci/g). [Back]
c. An average smoke detector for domestic use contains about 0.29 micrograms of Am-241 (in the form of americium dioxide), so its activity is around 37,000 Bq (or about 1 µCi). [Back]
d. Am-241 emits low energy gamma rays of 60 keV. The Am-241 gamma dose constant of 3.14 mSv/hr at a distance of one metre from a certain amount – 37 GBq – of Am-241. This gives an annual dose at one metre of 27 µSv/yr for an average household smoke detector – around 100 times lower than the dose from natural background radiation. [Back]
e. See the the Australian Radiation Health Committee's Statement on Disposal of Domestic Smoke Detectors (November 2001). [Back]
Ionization Technology webpage on the U.S. Environmental Protection Agency website (www.epa.gov)
Radioactivity in Domestic Smoke Alarms Fact Sheet on Australian Radiation Protection and Nuclear Safety Agency (ARPANSA) website (www.arpansa.gov.au)
How Smoke Detectors Work on HowStuffWorks website (www.howstuffworks.com)
Smoke Detectors and Americium-241, Canadian Nuclear Society (CNS) Educational Brochure on CNS website (www.cns-snc.ca)
Related information pages
Processing of Used Nuclear Fuel